Sorry, but the way I see it power curves are irrelevant abstractions.
The fact is that the Spitfire can go 182mph and still climb. That isn't going to achieve it's maximum climb rate, but so what. Maximum climb rates don't really play any particular role here. The fact is that at 182mph the Spitfire LF.Mk IX is climbing at something like 4,500fpm and the Fw190A is climbing at something like 4,000fpm. Those are sustained numbers at 182mph, not zooms.
In order to achive that rate of climb the Spitfire needs a greater angle of climb. If it lessens the angle of climb to match the Fw190's angle of climb it will now be able to travel faster than 182mph as the power needed to climb at 4,500fpm at 182mph is more than the power needed to climb at the lower angle and 182mph.
Now, the only way for what you are saying to work is if the Spitfire, when matching the Fw190's angle of climb, climbs at a lower rate than the Fw190 does.
Any other scenario would either have the Spitfire's top speed far lower than it was or allow the Spitfire to directly follow the Fw190's vector.