Yeah when the Shuttle goes to Hubble I believe thats the furthest that the shuttle goes out away from the Earth, 400 miles IIRC.
Also a little bit of trivia for ya, but this was the last space shuttle launch that won't be going to the ISS, because it's not that much longer and the shuttles are being retired and replaced with the new space vehicle.
The best was seeing a night launch a few years back. VERY impressive.
Yeah a couple years ago I was in Houston and got to see the shuttle fly over head on it's way back to land at night, that was really cool, you get to see the glowing plasma trail it leaves behind in the sky, and man that thing is moving fast, it traveled across the visible sky in about a min, I believe they said it was still going about 12,000mph when it was over head.