I've never used that temp monitor before so I'm assuming "Value" is the current temp. If so, yes, those temps are fine. CPU is average for a C2D (or from the reported temps I've seen it's average), the CPU is fine up to about 70-80C but normally anything over 65C isn't great. GPU is a little warm, but I have only mine (GTX 260) to compare it to, but either way 63C is fine. GPUs are normally able to get up to 100C but most try to stay under 65-70C, best not to run hot.

If that was taken after closing the game then the temps would have dropped a good bit already though. Best way to get an accurate reading is get an On-sceen Display for temps or something that will make charts during gameplay monitoring temps.