I have a 1974 lambretta with a high compression nicosil alloy barrell and head 180cc, exspansion chamber clubman. ( I have broke two cranks using this kit
)
From my experience of skimmed barrel head it might be that you require a thicker gasket to the cylinder head.
with the Mugello skimmed/or squished head you are supplied with various head gaskets depending on how far you want to increase the compression.
Compression closing the gap seems a little excessive, if such pressure was excerted on the plug it would strip the alloy head plug thread before cloing the gap. ( i have had this happen where by the plug becomes a bullet and fire's across the workshop)
I have seen melted plugs and squashed plugs but not from compression.
My Lambretta require a new up gear and ugraded clutch to cope with increased compresson.
Is there variants of spark plugs for said barrel?
I would be interested to see pics of you stripping barrel down, many heas together might be able to help you with this problem.
I remember rebuilding my engine and forgetting to put my a new roller bearing in the crank
it still looks at me that caged bearing when I am looking for something