We have no control over vertical sync. The video card handles that. If Windows/DirectX has decided to use the slowest rate between the two monitors, there is really nothing we can do about it.
If it is using the slower rate because of the slower monitor, then try removing that monitor and see if it changes.
Also note, many, many LCD monitors claim 120Hz refresh rates when in reality they are running at 60Hz and using software to spoof the rest of the 60Hz.