They had enough fuel to shift between orbits but not much more than that, so trajectory is primarly determined by their initial velocity leaving the atmosphere. The optimal trajectory (from a fuel consumption/weight standpoint) is the one where you make the least amount of corrections with your motors. So maneuvering a spacecraft is pretty much the same as maneuvering an unpowered satellite.
Ideally you only use motors to:
1. Leave the atmosphere.
2. Correct errors in your flight path caused by the difference between real life and your calculations.
3. Shift between stable trajectories.