Whitehawk,
As you know, this motherboard has 2 IDE connectors and a whole bunch of Serial ATA connectors. Since you don't have a serial ATA hard drive, you can ignore those S-ATA connectors.
Here's how you hook up your IDE devices(Hard drives, CD-ROMs):
If you have one hard drive, hook that up to the primary IDE connector with one of the IDE cables provided with the MB. If you have two hard drives, you'll need to set the jumpers on the hard drives so that one is the "master" and the other one is the "slave". You'll notice on the IDE cables that there are three connectors, one on each end, and one in the middle. One of those ends plugs into the primary IDE connector on the MB.
If you have only one hard drive, plug the connector on the other end of the IDE cable into it, leaving the connector in the middle of the IDE cable empty.
If you have two hard drives, then after setting the jumpers (see above), plug the "master" hard drive into the connector in the middle of the IDE cable. Plug the "slave" hard drive into the connector on the end of the cable.
For your CD-ROM devices, do exactly the same procedure as above, except using the secondary IDE connector on the MB.
Remember: Hard drives go on the Primary IDE connector on the MB, and the CD-ROM devices go on the Secondary IDE connector.