Just thought I would update on what happened after I tried again (Had to wait for the Arcticsilver to arrive!)
I refitted the AMD64x2 4200 and never once got a clean boot through the BIOS/CMOS. Always a checksum error - defaults loaded.
I tried booting with each one of four sticks of RAM I have and sometimes tried to save at a higher voltage setting. - No difference what so ever.
I tried with flashing to BIOS 1009 and 1302 still no difference (NB both support the processor).
In the end, I put the single core CPU back in and all four sticks of 512MB RAM and it ran perfectly straight away after spend most of the day being messed aound with the x2 CPU in. I have posted on some technical forums so I will have to see if any new ideas come of it, but for now I am stumped