Check to see if enough water is in boiler. Gauge, if working, should be around 15-18 psi.
Usually even if you add more water, air will still be a problem if so it needs to be purged.
Of course this should be done by someone qualified to do it, as you are dealing with scalding hot water, but this is a good way to purge the air from your heating zones.
I always turn off the boiler ahead of time to let it cool down a bit. Both so I dont get burned and also so Im not dumping cold water into the boiler.
This is a common older setup, although many systems today have the circulators on the supply header.
This is how I purge the zones. One at a time. Its good to have another person to hold the hoses in the bucket so they dont fly around the room making a mess. If you have antifreeze in the system, use antifreeze instead of water in the bucket mixed to desired amount h2o/antifreeze.
Make sure you dont overpressure the boiler. I usually go no higher than 25lbs to keep 30lb relief valve from popping off.
Again, this should be done by someone who knows what they are doing, but if in a jam, and you are careful, this is how I'd do it.