Actually its the opposite. The 190D has total and complete control of the fight regardless of the opposing pilot. However as pointed out elsewhere its the Indian not the arrow that matters the most. The pilots you mentioned are formidable in any plane. The 190D has the advantage that it minimizes an opponents ability to take control of a fight. so the spitty (or 109) driver is left to a set of defensive trap options. the better the pilot the better the chance to successfully set a trap. But a spit driver in an inferior position vs a 190D (or pony, hog, 109K etc) is totally dependent on the relative ability, experience and patience of the 190 driver.
Your much more likely to find me fighting a spitty in an SBD then a 190 but the principles are the same. Your matching the Indian vs the arrow. When you happen to find an arrow with an Indian on board your generally in a world of hurt. but to me in a 190D a spitfire of any flavor (except the 14) is just another minnow.
Now a spitfire in a superior position is an exceptionally hard enemy to overcome....even more so with any of the exceptional pilots above.