remember to thin it to the consistency of milk...
practice.
let the paint dry at least 48 hrs before you handle it again or you may burn fingerprints in it.
wash the plastic in mild detergent and let dry before painting.
easier to handle parts for painting *if* you can leave them on the sprues and touch up after you cut them off.
some people prefer the acrylics... personally i use the enamels. i like model master (upscale testors).
start the spray *before* you start your pass and keep it going until you go past the end.
don't spray too close or too far away.... running or splattering may result.
2-3 light coats over a few days would be better than trying for one coat all at once.
use a compressor (and hopefully have a moisture trap and regulator). co2 tank would be next option, followed last by canned air.
always, always clean the tip and nozzle after you're done.
be willing to strip the paint job if you're not happy with it.
if you're gonna mask any parts, use low-tack tape.
you might want to finish it off with a coat of dullcote... glosscote can make it look too "toyish."
there's more that i can't think of atm... but here's a good geenral idea site...
http://www.angelfire.com/oh3/pmodels/paasche.htm