From what I read, it seems the resons 4 the excellent perf in climbing and maneuverability of the Macchis were the perfect aerodynamic and first of all the wing.
Dont'know exactly wich was the "secret" of the Macchi's wing, unfortunatly I never was able to find a anything with a deep descritpion of the wing.
It seems that the profile and his developement in the lenght of the wing were something particular.
Probably the result of all this was a really low drag and therefore better performances by same engine power.
The Luftwaffe did a test comparing Bf109G4, Fw190A5, Fiat G55, Mc205, Reggiane Re2005 and found the 205 climbing with the 109 and maneuvering better (among other things, LW said the 205 required less power in the turns than the 109, dunno exactly what that means).
Jg77 used the 205 in winter '43, judging it as excellent.
It must be said that Mario Castoldi, the designer of Macchi, was an excellent engineer, he had a long experience in designing race planes (the Macchi M39 which won the Schneider Trophy in 1926 and the superb seaplane Mc72, wich reached 711km/h, world record 4 seaplanes) and knew very well how to deal with aerodynamic, wing profiles, drag etc.
The Mc20x serie were the masterpieces of Castoldi.
v-twin