Usually it's best to have the fans blow air out. Fans that blow air in are for the most part used to direct the airflow to a desired point.
Although both your PSU and GPU blow out, they produce heat themselves, thus also heating the inside of your case. Putting an extra outbound fan as high as possible will make cool air flow all through your case, cooling also your RAM sticks and HDD's. In a good case there are a lot of ventilation gaps for the intake, in better ones even with dust filters, so there is no need to force air in.