Sorry Floob, but although you claim to understand the concept, your statements aren't supporting that. I have to ask if you have ever shot a tracer round into a full can of gasoline. I have, multiple calibers. A completely full 5gal can of regular gasoline won't ignite, but a 1/2 full can will blow if the vapors in the empty space get ignited. It's pretty energetic too.
Also, gasoline doesn't require combustion to ignite. Just like every other flammable substance it requires a heat source and oxygen. Once again, it is not the liquid that ignites, it is the vapor layer that is created as the liquid evaporates. When you see a gasoline fire, it's not the liquid that is burning, it's the vapor layer on top of the liquid that is burning. That effect is very visible if you pour gasoline on a flat surface then light it. A lit cigarette can ignite gasoline vapors, not as easily as a lit match but it can be done.