Adding 2x2 is fine. You won't notice any big difference having 12 GB, even less in the game. I noticed quite a leap going from 4 to 8 GB especially in responsiveness. More than 8 GB is needed mostly if you do heavy image or video editing.
If you can't find the same brand, try to find the same specs. Or, depending on the price, get a set of a suitable 2x4 and sell the current ones.
DDR3 1600 (PC3 12800)
Timing 6-8-6-24
Cas Latency 6
Voltage 1.65V