The fact is that both the Mk 14 and 16 did have bubble canopies - that is, production of both mks eventually had bubble canopies.
Spitfire variant numbers were not really in chronological order, and in many instances were not made to replace a previous mk, so it doesn't necessarily follow that a Mk 16 will have all of the refinements of lower numbered variants. The Mk 16 for instance, was a Mk 9 in all respects, but it used the Packard version of the Merlin engine instead of Rolls Royce, presumably because there was a shortage of Rolls Royce Merlins - there were enough differences in the engine (imperial vs metric measurements, etc) that a different Mk number was needed to ensure correct logistical support. The Mk 9 was still in production at that point, and eventually both the 9 and 16 were produced with bubble canopies.
Mike