In most aircraf there is a point where increasing the angle of your dive doesn't give you an equal increase in airspeed.
Think of it this way - at -4000'/min. say the Fw 190A-5 can hit a speed of 525. At -5200'/min. that speed may be 531 or so. Number are hypothetical - I haven't done the testing.
So if you and the Spitfire IXe are both at 10,000'...if you dive too steep for too long - he's gonna get you. Because when you are on the deck and starting to slow down, he's still got 2000' of 'diving room' to boost his speed. Does that make sense?
Spitfires are very clean in terms of aerodynamics, even if they are ugle as sin.

Dive at 2000'/min., maybe 3000'/min. if you need to get out of gun range. If he's getting really close, scissor him (V or H or both) until you are both down to 250 MPH IAS or so, and *then* out dive/out accelerate him. But if you let him stay in roughly a straight line coming off of a dive, he's going to keep his speed very very well.
When conducting maneuvers in the vertical at high speed, it's very easy to lose track of your instrumentation and dive too steep, etc. Keep a close eye on the VSI and don't let it get crazy on you. Also keep a close eye on the accelerometer. A high % of AH MA pilots blow a great deal of altitude by diving too steep, as opposed to using the optimal angle of dive (in terms of acceleration).
Mike/wulfie